Applied Thermodynamics of Fluids by
Published under the auspices of both IUPAC and its affiliated body, the International Association of Chemical Thermodynamics (IACT), this book will serve as a guide to scientists or technicians who use equations of state for fluids. Concentrating on the application of theory, the practical use of each type of equation is discussed and the strengths and weaknesses of each are addressed. It includes material on the equations of state for chemically reacting and non-equilibrium fluids which have undergone significant developments and brings up to date the equations of state for fluids and fluid mixtures. Applied Thermodynamics of Fluids addresses the needs of practitioners within academia, government and industry by assembling an international team of distinguished experts to provide each chapter. The topics presented in the book are important to the energy business, particularly the hydrocarbon economy and the development of new power sources and are also significant for the application of liquid crystals and ionic liquids to commercial products. This reference will be useful for post graduate researchers in the fields of chemical engineering, mechanical engineering, chemistry and physics.
Continuum Thermodynamics (V77): Foundations by
This book is a unique presentation of thermodynamic methods of construction of continuous models. It is based on a uniform approach following from the entropy inequality and using Lagrange multipliers as auxiliary quantities in its evaluation. It covers a wide range of models — ideal gases, thermoviscoelastic fluids, thermoelastic and thermoviscoelastic solids, plastic polycrystals, miscible and immiscible mixtures, and many others. The structure of phenomenological thermodynamics is justified by a systematic derivation from the Liouville equation, through the BBGKY-hierarchy-derived Boltzmann equation, to an extended thermodynamics. In order to simplify the reading, an extensive introduction to classical continuum mechanics and thermostatics is included. As a complementary volume to Part II, which will contain applications and examples, and to Part III, which will cover numerical methods, only a few simple examples are presented in this first Part. One exception is an extensive example of a linear poroelastic material because it will not appear in future Parts.The book is the first presentation of continuum thermodynamics in which foundations of continuum mechanics, microscopic foundations and transition to extended thermodynamics, applications of extended thermodynamics beyond ideal gases, and thermodynamic foundations of various material theories are exposed in a uniform and rational way. The book may serve both as a support for advanced courses as well as a desk reference.
Thermodynamics by
This book places thermodynamics on a system-theoretic foundation so as to harmonize it with classical mechanics. Using the highest standards of exposition and rigor, the authors develop a novel formulation of thermodynamics that can be viewed as a moderate-sized system theory as compared to statistical thermodynamics. This middle-ground theory involves deterministic large-scale dynamical system models that bridge the gap between classical and statistical thermodynamics. The authors' theory is motivated by the fact that a discipline as cardinal as thermodynamics--entrusted with some of the most perplexing secrets of our universe--demands far more than physical mathematics as its underpinning. Even though many great physicists, such as Archimedes, Newton, and Lagrange, have humbled us with their mathematically seamless eurekas over the centuries, this book suggests that a great many physicists and engineers who have developed the theory of thermodynamics seem to have forgotten that mathematics, when used rigorously, is the irrefutable pathway to truth. This book uses system theoretic ideas to bring coherence, clarity, and precision to an extremely important and poorly understood classical area of science.
Thermodynamics of Surface Phenomena by
The book is concerned with the main assumptions of the theory of Gibbs capillarity theory and fundamental thermodynamic equations, derived by the method of the finite thickness layer. Special attention is given to applied aspects of the thermodynamic theory of surface phenomena. Methods for calculating adsorption in multicomponent solutions are examined in detail. Systems of equations for calculating adsorption in real multicomponent systems from the concentration dependence of surface tension are derived for the first time. Experimental data on surface tension and density in binary and multicomponent systems are presented. Analysis of the results is used to develop methods for predicting the surface properties of multicomponent systems from the data on the properties of binary melts.
Chemical Energy and Exergy by
This book is a beginners introduction to chemical thermodynamics for engineers. In the textbook efforts have been made to visualize as clearly as possible the main concepts of thermodynamic quantities such as enthalpy and entropy, thus making them more perceivable. Furthermore, intricate formulae in thermodynamics have been discussed as functionally unified sets of formulae to understand their meaning rather than to mathematically derive them in detail. In this textbook, the affinity of irreversible processes, defined by the second law of thermodynamics, has been treated as the main subject, rather than the equilibrium of chemical reactions. The concept of affinity is applicable in general not only to the processes of chemical reactions but also to all kinds of irreversible processes. This textbook also includes electrochemical thermodynamics in which, instead of the classical phenomenological approach, molecular science provides an advanced understanding of the reactions of charged particles such as ions and electrons at the electrodes. Recently, engineering thermodynamics has introduced a new thermodynamic potential called exergy, which essentially is related to the concept of the affinity of irreversible processes. This textbook discusses the relation between exergy and affinity and explains the exergy balance diagram and exergy vector diagram applicable to exergy analyses in chemical manufacturing processes. This textbook is written in the hope that the readers understand in a broad way the fundamental concepts of energy and exergy from chemical thermodynamics in practical applications. Finishing this book, the readers may easily step forward further into an advanced text of their specified line. - Visualizes the main concepts of thermodynamics to show the meaning of the quantities and formulae. - Focuses mainly on the affinity of irreversible processes and the related concept of exergy. - Provides an advanced understanding of electrochemical thermodynamics.
Understanding Thermodynamics by
Grappling with the first and second laws of thermodynamics can test the intellectual mettle of even the most dedicated student of the physical sciences. Approaching the subject for the first time may raise more queries and doubts than are usually handled in the basic, straightforward textbook. Based on a series of lectures delivered to 500 sophomore engineering students at Rensselaer Polytechnic Institute, Dr. Van Neer's clear, lucid treatment is readily comprehensible by undergraduate-level science and engineering students. His language is informal, his examples are vivid and lively, his perspective is fresh. This book, a companion to a basic textbook, discusses thermodynamics, a topic of profound importance in the study of physics, in a manner which elucidates fundamental concepts and demonstrates their practical applicability. In these increasingly energy-conscious and costly times, as traditional energy sources are being depleted and revolutionary new sources are contemplated, appreciating the consequences of the laws of thermodynamics is more than a fascinating avenue of intellectual inquiry: it is a pragmatic concern imperative to all -- students, scientists, engineers, technicians, politicians, businessmen, and anyone facing the energy challenges of the future. Here is help understanding concepts which will prove all-important in the next century. Dr. H. C. Van Ness is a distinguished professor of chemical engineering at Rensselaer Polytechnic Institute and co-author of several textbooks on thermodynamics. He is an unsurpassed as an expert in the field.